Tautomerization and Dissociation of Dimethyl Phosphonate Ions(CH3O)2P(H)=O•+:Theory and Experiment in Concert Academic Article uri icon

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abstract

  • The unimolecular gas phase chemistry of the title ion,(CHThe identity of the ions was probed by tandem mass spectrometry methods. These include MI (metastable ion) or CID (collision induced dissociation) spectra, consecutive MI/CID and CID/CID spectra, NRMS (neutralization-reionization mass spectra), NR/CID and CIDI (collision induced dissociative ionization) spectra, time-resolved CID spectra and deuterium labelling. The energetics of the CHTheory and experiment yield a consistent potential energy profile that describes the isomerization and low energy dissociation chemistry of ions

authors

  • Heydorn, LN
  • Ling, Y
  • Oliveira, G de
  • Martin, JML
  • Lifshitz, C
  • Terlouw, Johan

publication date

  • January 1, 2001