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The role of hydrogen-bridged radical cations in...
Journal article

The role of hydrogen-bridged radical cations in the dissociation of ionized glycolaldehyde [HOCH2CHO]+•

Abstract

Ab initio molecular orbital theory calculations combined with mass spectrometric experiments show that the dissociation of metastable glycolaldehyde radical cations occurs at the thermochemical threshold and that this process proceeds via a CHO bridged ion [CH2O(H)…H…CO]+•.

Authors

Postma R; Ruttink PJA; Van Lenthe JH; Terlouw JK

Journal

Chemical Physics Letters, Vol. 156, No. 2-3, pp. 245–250

Publisher

Elsevier

Publication Date

March 1989

DOI

10.1016/s0009-2614(89)87128-3

ISSN

0009-2614