The Phosphorus Ylide CH₂PH₃ is Stable in the Gas Phase Journal Articles

abstract

• By neutralization–reionization mass spectrometry (NRMS), the parent compound of the phosphorus ylides, methylenephosphorane CH2PH3, can be generated and unequivocally characterized. This substance cannot be “bottled” but is stable under the conditions of the NRMS experiment, and its properties correspond with those proposed by theory.

authors

• Keck, Helmut
• Kuchen, Wilhelm
• Tommes, Peter
• Terlouw, Johan
• Wong, Thomas

status

• published 

publication date

• January 1992

has subject area

• 03 Chemical Sciences (FoR)
• Organic Chemistry (Science Metrix)

published in

• Angewandte Chemie International Edition  Journal

keywords

• CATIONS
• Chemistry
• Chemistry, Multidisciplinary
• GENERATION
• IONS
• MOLECULES
• NEUTRALIZATION
• NRMS
• PHOSPHINE
• Physical Sciences
• REIONIZATION MASS-SPECTROMETRY
• Science & Technology

Digital Object Identifier (DOI)

• 10.1002/anie.199200861

start page

• 86

end page

• 87

volume

• 31

issue

• 1