Journal article
Generation of Carbamic Acid (NH2CO2H) and its Radical Cation as Stable Species in the Gas Phase
Abstract
Thermolysis of ammonium carbamate yields the hitherto unknown free carbamic acid (H2N–CO–OH), which is characterized by means of mass spectrometric methods. In the gas phase high energy barriers prevent the spontaneous dissociation of both neutral carbamic acid (1) and its radical cation (1⊕⨀).
Authors
Van den Berg KJ; Lebrilla CB; Terlouw JK; Schwarz H
Journal
CHIMIA International Journal for Chemistry, Vol. 41, No. 4,
Publisher
Swiss Chemical Society
DOI
10.2533/chimia.1987.122
ISSN
0009-4293