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Generation and characterization of ionic and...
Journal article

Generation and characterization of ionic and neutral dihydroxy boron B(OH)2+/0 in the gas phase

Abstract

The dicoordinated borinium ion, dihydroxyborinium, B(OH)2+ is generated from methyl boronic acid CH3B(OH)2 by dissociative electron ionization and its connectivity confirmed by collisional activation. Neutralization–reionization (NR) experiments on this ion indicate that the neutral B(OH)2 radical is a viable species in the gas phase. Both vertical neutralization of B(OH)2+ and reionization of B(OH)2 in the NR experiment are, however, …

Authors

Srinivas R; Vivekananda S; Blanksby SJ; Schröder D; Schwarz H; Fell LM; Terlouw JK

Journal

International Journal of Mass Spectrometry, Vol. 197, No. 1-3, pp. 105–111

Publisher

Elsevier

Publication Date

2 2000

DOI

10.1016/s1387-3806(99)00223-7

ISSN

1387-3806