Metal Ion Hydrocarbon Bidentate Bonding in Alkyl Acetates, Methyl Alkanoates, Alcohols and 1-Alkenes: A Comparative Study

The relative affinity of the monovalent metal ions Li⁺, Na⁺, Cu⁺ and Ag⁺ towards a series of aliphatic alkyl acetates and some selected 1-alkenes (P) was examined using the kinetic method. A detailed analysis of the dissociation characteristics of a series of mixed metal-bound dimer ions of the type P₁-M⁺-P₂ and the evaluated proton affinities (PAs) of the monomers shows that the affinity of the cation towards long-chain alkyl acetates and …