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Structural analysis of diols by electrospray mass...
Journal article

Structural analysis of diols by electrospray mass spectrometry on boric acid complexes

Abstract

A method is presented to characterize diols using negative ion electrospray (ES) mass spectrometry in combination with collision-induced dissociation tandem mass spectrometry (MS/MS). The analyte diol is added to a solution containing an ethylene glycol/boric acid [2:1] complex and then subjected to infusion ES. The following boric acid complexes are formed: (i) a complex with two ethylene glycol molecules, (ii) a mixed ethylene glycol/analyte …

Authors

Ackloo SZ; Burgers PC; McCarry BE; Terlouw JK

Journal

Rapid Communications in Mass Spectrometry, Vol. 13, No. 23, pp. 2406–2415

Publisher

Wiley

Publication Date

December 15, 1999

DOI

10.1002/(sici)1097-0231(19991215)13:23<2406::aid-rcm806>3.0.co;2-z

ISSN

0951-4198