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Effect of UV radiation damage in air on polymer...
Journal article

Effect of UV radiation damage in air on polymer film thickness, studied by soft X-ray spectromicroscopy

Abstract

The thicknesses of thin films of polystyrene (PS), poly(methyl methacrylate) (PMMA), and perfluorosulfonic acid (PFSA) were measured by Ultraviolet Spectral Reflectance (UV-SR) and Scanning Transmission X-ray Microscopy (STXM). At high doses, the UV irradiation in air used in the UV-SR method was found to modify the chemical structures of PS and PMMA (but not PFSA), leading to thinning of these polymer films. The chemical changes caused by …

Authors

Melo LGA; Hitchcock AP; Susac D; Stumper J; Berejnov V

Journal

Physical Chemistry Chemical Physics, Vol. 20, No. 24, pp. 16625–16640

Publisher

Royal Society of Chemistry (RSC)

Publication Date

June 20, 2018

DOI

10.1039/c7cp08621k

ISSN

1463-9076