Journal article
Structural and theoretical studies of Xe(OChF5)2 and [XeOChF5][AsF6] (Ch = Se, Te)
Abstract
The XeOSeF5+ cation has been synthesized for the first time and characterized in solution by 19F, 77Se and 129Xe NMR spectroscopy and in the solid state by X-ray crystallography and Raman spectroscopy with AsF6− as its counter anion. The X-ray crystal structures of the tellurium analogue and of the Xe(OChF5)2 derivatives have also been determined: [XeOChF5][AsF6] crystallize in tetragonal systems, P4/n, a=6.1356(1)Å, c=13.8232(2)Å, …
Authors
Fir BA; Mercier HPA; Sanders JCP; Dixon DA; Schrobilgen GJ
Journal
Journal of Fluorine Chemistry, Vol. 110, No. 2, pp. 89–107
Publisher
Elsevier
Publication Date
August 2001
DOI
10.1016/s0022-1139(01)00416-x
ISSN
0022-1139