Journal article
Coordination of KrF2 to a Naked Metal Cation, Mg2+
Abstract
Examples of coordination compounds in which KrF2 functions as a ligand are very rare. In contrast, XeF2 provides a rich coordination chemistry with a variety of main-group and transition metal cations. The reactions of Mg(AsF6 )2 and KrF2 in HF or BrF5 solvent have afforded [Mg(KrF2 )4 (AsF6 )2 ] and [Mg(KrF2 )4 (AsF6 )2 ]⋅2 BrF5 , respectively, the first examples of a metal cation ligated by KrF2 . Their X-ray crystal structures and Raman …
Authors
Lozinšek M; Mercier HPA; Brock DS; Žemva B; Schrobilgen GJ
Journal
Angewandte Chemie International Edition, Vol. 56, No. 22, pp. 6251–6254
Publisher
Wiley
Publication Date
May 22, 2017
DOI
10.1002/anie.201611534
ISSN
1433-7851