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Biaryl Ketones by Suzuki–Miyaura Cross‐Coupling of...
Journal article

Biaryl Ketones by Suzuki–Miyaura Cross‐Coupling of Organotrifluoroborates and Acyl Chlorides

Abstract

A procedure for the synthesis of biaryl ketones by a palladium‐catalyzed Suzuki–Miyaura cross‐coupling reaction between phenyltrifluoroborates and benzoyl chlorides is described. Organotrifluoroborates are unique to other cross‐coupling reagents as they have a high functional‐group tolerance and are moisture‐stable. Moderate to excellent yields were obtained for all substrates tested.

Authors

Forbes AM; Meier GP; Jones‐Mensah E; Magolan J

Journal

European Journal of Organic Chemistry, Vol. 2016, No. 17, pp. 2983–2987

Publisher

Wiley

Publication Date

6 2016

DOI

10.1002/ejoc.201600199

ISSN

1434-193X