abstract
- An efficient 8-step enantioselective total synthesis of (+)-angelmarin, starting from commercially available umbelliferone, has been achieved. Key reactions include olefin cross-metathesis and a Shi epoxidation-cyclization sequence.
Total Synthesis of (+)-Angelmarin
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Overview
authors
status
publication date
- July 17, 2009
has subject area
- 0304 Medicinal and Biomolecular Chemistry (FoR)
- 0305 Organic Chemistry (FoR)
- Coumarins (MeSH)
- Cyclization (MeSH)
- Organic Chemistry (Science Metrix)
- Plant Extracts (MeSH)
- Stereoisomerism (MeSH)
- Umbelliferones (MeSH)
published in
- Journal of Organic Chemistry Journal