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Kinetic Behavior of Atom Transfer Radical...
Journal article

Kinetic Behavior of Atom Transfer Radical Polymerization of Dimethacrylates

Abstract

Abstract Summary: The reaction behavior and kinetics of the atom transfer radical polymerization (ATRP) of poly(ethylene glycol) dimethacrylates (PEGDMA) were studied with respect to polymerization rate, vinyl conversion and the development of a crosslinked network. The polymerization rates were much slower than the corresponding conventional free radical polymerizations with the ATRP systems exhibiting milder autoacceleration. The linear …

Authors

Yu Q; Zhang J; Cheng M; Zhu S

Journal

Macromolecular Chemistry and Physics, Vol. 207, No. 3, pp. 287–294

Publisher

Wiley

Publication Date

February 3, 2006

DOI

10.1002/macp.200500378

ISSN

1022-1352